Semiconductor device having copper alloy leads

ABSTRACT

A semiconductor device having leads of high strength and elongation and which consist essentially of a copper alloy that contains 0.05-1% of Cr, 0.005-0.3% of Zr, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of Si and 0.001-0.3% of at least one element selected from the group consisting of P, Mg, Al, Zn and Mn, with the balance being Cu and no more than 0.1% of incidental impurities, the percent being on a weight basis. The invention also provides a semiconductor device having leads of high strength and elongation and which consist essentially of a copper alloy that contains either 0.05-1% of Cr or 0.005-0.3% of Zr or both, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of Si and which further contains one or more of 0-2% of a metal selected from the group consisting of Fe, Co and Be, 0-1% of a metal selected from the group consisting of Mg, Al, Zn, Mn, B, P, Y and a rare earth element, and 0-2% of a metal selected from the group consisting of Nb, V, Ta, Hf, Mo and W, the percent being on a weight basis, with the balance being copper and incidental impurities, and which has a structure wherein the average grain size of any eutectic crystal present is no more than 10 μm, the average grain size of any precipitate present is no more than 0.1 μm, and the average size of any crystalline grains present is no more than 50 μm.

This application is a continuation-in-part application Ser. No. 903,514 filed Sept. 3, 1986. U.S. Pat. No. 4,749,548.

BACKGROUND OF THE INVENTION

1. Field of Use

The present invention relates to semiconductor devices such as ICs and LSIs having copper alloy leads.

2. Prior Art

Copper alloy lead materials for use in semiconductor materials are required to have the following properties:

(i) good workability for stamping;

(ii) heat resistance high enough to avoid thermal distortion and softening upon thermal bonding or thermal diffusion compression of a semiconductor device;

(iii) rapid heat dissipation and good electrical conductivity; and

(iv) strength and elongation great enough to avoid bending or failure due to the repeated bending that may occur during transportion of a semiconductor device or upon its installation in an electrical machine.

Characteristically, Cu alloy lead materials intended for use in specific fields are required to have the following values:

a tensile strength of 40 kgf/mm² or more as an index of strength;

an elongation of 4% or more as another index of strength;

an electrical conductivity of 50% IACS or more as an index of heat dissipation and conductivity; and

a softening point of 400° C. or higher as an index of heat resistance.

Many products have been proposed as Cu alloy lead materials satisfying these requirements and are currently in commercial use.

However, with the ever increasing demand for a higher packing density in modern semiconductor devices, Cu alloy lead materials are required to exhibit even higher degrees of strength and elongation in addition to high heat resistance and good heat dissipation and electrical conductivity. Therefore, it is strongly desired to develop Cu alloy lead materials that satisfy these requirements for performance.

SUMMARY OF THE INVENTION

The primary object of the present invention is to provide semiconductor devices having copper alloy leads material that display advantageous higher degrees of strength and elongation and which retain other advantageous characteristics of prior art semiconductor devices.

The present invention provides the following embodiments:

(1) A semiconductor device having leads of high strength and elongation which consist essentially of a copper alloy that contains 0.05-1% of Cr, 0.0005-0.3% of Zr, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of

Si and 0.001-0.3% of at least one element selected from the group consisting of P, Mg, Al, Zn and Mn, with the balance being Cu and no more than 0.1% of incidental impurities, the percent being on a weight basis. Preferably, said copper alloy contains 0.005-0.1% of Zr, 0.05-1% of Ni, 0.05-1% of Sn, 0.05-1% of Ti, 0.001-0.1% of Si, the percent being on a weight basis.

(2) A semiconductor device having leads of high strength and elongation which consist essentially of a copper alloy that contains either 0.05-1of Cr or 0.005-0.3% of Zr or both, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of Si and which further contains one or more of 0-2% of a metal selected from the group consisting of Fe, Co and Be, 0-1% of a metal selected from the group consisting of Mg, Al, Zn, Mn, B, P, Y and a rare earth element, and 0-2% of a metal selected from the group consisting of Nb, V, Ta, Hf, Mo and W, the percent being on a weight basis, with the balance being copper and incidental impurities, and which has a structure wherein the average grain size of any eutectic crystal present is no more than 10 μm, the average grain size of any precipitate present is no more than 0.1 μm, and the average size of any crystalline grains present is no more than 50 μm. Preferably, said copper alloy contains 0.005-0.1% of Zr, 0 05-1% of Ni, 0.05-1% of Sn, 0.05-1% of Ti, 0.001-0.1% of Si and which further contains one or more of 0.005-2% of a metal selected from the group consisting of Fe, Co and Be, 0.001-1% of a metal selected from the group consisting of Mg, Zn, Mn, B, P, Y and a rare earth element, and 0.005-2% of a metal selected from the group consisting of Nb, V, Ta, Hf, Mo and W.

In an embodiment of the present invention the lead may be manufactured by hot rolling an ingot, quenching, cold rolling, and aging to attain a structure wherein the average grain size of any eutectic crystal present is no more than 10 μm compared with the conventionally observed range 20-100 μm, the average gain size of any precipitate present is no more than 0.1 μm compared with the conventionally observed range of 0.5-3 μm, and the average size of any crystalline grains present is no more than 50 μm compared with the conventionally observed range of 60-200 μm. A copper alloy lead material having such a line structure and capable of attaining the aforementioned object of the present invention may also be to produced form a composition that further contains 5-60 ppm of C in addition to the components described in (2), with the balance being copper and incidental impurities, provided that the O₂ content is no more than 35 ppm. This variant of the alloy composition (2) may be subjected to quenching after hot rolling and aging after cold rolling.

BRIEF DESCRIPTION OF THE DRAWINGS

The drawing is a schematic plan view of a semiconductor element having the leads of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

The semiconductor device is shown as an encapsulated integrated circuit (IC) 1 which has a semiconductor element 4 and connecting leads 3 leading to a lead frame(not shown). The IC 1, the semiconductor element 4 and the lead frame (not shown) can be of conventional structure well known in technology and do not form part of the present invention.

The criticality of the compositional range of each of the elements in the Cu alloy leads of the present invention is hereunder described.

(a) Cr and Zr

These elements are capable of providing improved strength and heat resistance, but these effects are not attained if Cr is present in an amount of less than 0.05% or Zr is present in an amount of less than 0.005%. If the contents of Cr and Zr exceed 1% and 0.3%, respectively, the chance of formation of non-metallic inclusions increases to impair the platability and electrical conductivity of the alloy. Therefore, in order to attain the object of the present invention, the contents of Cr and Zr are specified to lie within the ranges of 0.05-1% and 0.005-0.3%, respectively.

(b) Li

Li serves not only as a deoxidizer but also as a grain refining agent to provide a higher degree of strength and elongation, resulting in better workability for stamping. These effects are not attainable if Li is present in an amount of less than 0.001%. If the Li content exceeds 0.05, a drop in electrical conductivity occurs. Therefore, in order to attain the object of embodiment 1 the present invention, the content of Li is specified to lie within the range of 0.001-0.05%. (c) P, Mg, Si, Al, An, and Mn.

These elements not only serve as a deoxidizer but also provide better platability, solderability and electrical conductivity. These effects are not attained if such elements are present in amounts of less than 0.001%. If their content exceeds 0.3%, their effectiveness has a tendency to decrease. Therefore, in order to attain the object of embodiment 1 the present invention, the content of one or more of these elements is specified to lie within the range of 0.001-0.3%.

If any incidental impurities are present in amounts exceeding 0.1%, at least one of the characteristics required of the lead material of the present invention is impaired. Therefore, in order to attain the object of the present invention, the content of incidental impurities must not exceed 0.1%.

(d) Ni and Sn

These elements are effective not only in providing improved strength but also in preventing any deformation or burring from occurring during stamping. They are optional elements for the purpose of the present invention, but if they are used at all, their effects are not attained if either one of them is present in an amount of less than 0.05%. If, on the other hand, the content of each element exceeds 1%, a drop in electrical conductivity occurs. Therefore, if Ni and Sn are used at all, in embodiment 1 the content of each of them preferably is within the range of 0.05-1%.

(e) Ti

Titanium is effective in providing improved heat resistance, platability (solderability) and electrical conductivity. It is not essential for the purpose of the present invention but, if it is used at all, the above-mentioned effects are not attained if the content of Ti is less than 0.05%. If the Ti content exceeds 1%, excessive precipitation occurs to cause a drop in electrical conductivity. Therefore, if Ti is used at all in embodiment 1, its content preferably is within the range of 0.05-1%.

(f) Si

Silicon not only serves as a deoxidizer but also provides improved heat resistance. Si is preferably present in an amount of not less than 0.001%. If the Si content exceed 0.1%, the rate of elongation decreases.. The Si content is specified to lie within the range of 0-0.1%, preferably 0.001-0.1% in embodiment 1.

(g) Metals of the first group, i.e., Ni, Sn, Fe, Co, Be

The metals of the first group are effective not only in providing improved strength but also in preventing the occurrence of deformation and burring during stamping These effects are not attained if the content of one of the metals of the first group is less than 0.005%. If one of these metals is present in an amount greater than 2%, a drop in electrical conductivity occurs. Therefore, if metals of the first group are used at all, their content is within the range of 0-2%, preferably 0-1%, and more preferably at least 0.005%.

(h) Metals of the second group, i.e. Mg, Al, Zn, Mn, B, P, Y and rare earth metals

Each of the metals of the second group not only serves as a deoxidizer but is also effective in providing improved electrical conductivity, platability and solderability if metals of the second group are used in embodiment 2, they are used in a amount of 0-1% and preferably in an amount of 0.001-1%.

(i) Metals of the third group, i.e. Nb, V, Ta, Hf, Mo and W

The metals of the third group are effective in providing improved strength and heat resistance. These effects are not attained if the content of one of the metals of the third group is less than 0.005%. If the content of a metal of the third group exceeds 2%, a drop in electrical conductivity occurs. Therefore, if a metal of the third group is used in embodiment 2, its content is within the range of 0-2% and preferably 0.005-2%.

(j) alloy structure

As already mentioned, the prior art Cu alloys from which lead materials for use in semiconductor devices have been made are characterized by the average grain size of the eutectic crystals ranging from 20 to 100 μm, the average grain size of the precipitate ranging from 0.5 to 3 μm, and the average size of the crystalline grains ranging from 60 to 200 μm. However, with such a coarse crystalline structure, a tensile strength of 50 kgf/mm² or higher and an elongation of 6% or higher cannot be attained and, in order to attain these values, the average grain size of any eutectic crystals, the average grain size of any precipitate and the average size of any crystalline grains must be reduced to 10 μm, 0.1 μm and 50 μm, respectively, or less. The increases in tensile strength and elongation combine together to achieve a pronounced improvement in the workability of the Cu alloy composition for stamping. Therefore, the above-specified values of tensile strength and elongation cannot be ensured if any one of the parameters for crystalline structure exceeds its upper limit.

(k) Carbon

Carbon forms carbides with other elements and serves to refine the crystalline grains and precipitates, thereby providing improved strength. The desired high strength is not attained if the carbon content is less than 5 ppm, but if its content exceeds 60 ppm, the plastic workability of the alloy is impaired. Therefore, in order to attain the object of the present invention, the content of carbon, if it is used at all, must be within the range of 5-60 ppm. However, if the content of oxygen as an incidental impurity exceeds 35 ppm, the carbon content drops below 5 ppm, which is detrimental to the purpose of ensuring the desired high tensile strength. Therefore, the content of oxygen as an incidental impurity must be held to 35 ppm or below.

The following examples are provided for the purpose of further illustrating the advantages of the Cu alloy lead material of the present invention but are in no sense to be taken as limiting.

EXAMPLE 1

Melts of Cu alloy having the compositions listed in Table 1 were formed in a conventional type of low-frequency channel induction-melting furnace. The melts were cast in a water-cooled mold to form ingots of 50 mm□ and 100 mm^(H), which were surface-polished and reduced in thickness to 11 mm by hot rolling which was started at predetermined temperatures within the range of 800°-950° C. After cooling with water, the top and bottom surfaces of each hot-rolled plate were polished thus reducing the plate thickness by 0.5 mm to achieve a final thickness of 10 mm. Subsequently, the plates were subjected to cycles of cold rolling and annealing under ordinary conditions to form strips of 0.3 mm in thickness. In the final step, the strips were annealed to eliminate any residual strain by holding them at predetermined temperatures within the range of 550°-600° C. By these procedures, sample Nos. 1-18 of the Cu alloy lead material of the present invention were fabricated. The tensile strength, elongation, electrical conductivity and softening point of each of these samples were measured, the results being shown in Table 1.

The data given in Table 1 shows that each of the samples 1 to 18 of the Cu alloy lead material of the present invention exhibited a tensile strength of 52 kgf/mm² or more, an elongation of 8.5% or more, an electrical conductivity of 80% IACS or more, and a softening point of 460° C. or higher. These values are indicative of the fact that the samples of the Cu alloy lead material of the present invention exhibit heretofore unattainable high levels of strength and elongation and yet satisfy the other requirements with respect to the characteristics which leads for use in semiconductor devices need to possess.

                                      TABLE 1                                      __________________________________________________________________________                                                               soften-              Composition (wt. %)                      tensile                                                                              elon-                                                                               conduc-                                                                              ing                  Sample                            impur- strength                                                                             gation                                                                              tivity                                                                               point                No.                                                                               Cr Zr  Li  P   Mg Si Al  Zn Mn ities                                                                              Cu (kgf/mm.sup.2)                                                                       (%)  (% IACS)                                                                             (°C.)         __________________________________________________________________________     1  0.052                                                                             0.12                                                                               0.031                                                                              0.11                                                                               -- -- --  -- -- 0.051                                                                              bal.                                                                              52    12.1 95    465                  2  0.50                                                                              0.14                                                                               0.028                                                                              0.12                                                                               -- -- --  -- -- 0.032                                                                              bal.                                                                              59    9.3  83    500                  3  0.96                                                                              0.16                                                                               0.031                                                                              0.10                                                                               -- -- --  -- -- 0.041                                                                              bal.                                                                              64    8.5  80    520                  4  0.48                                                                              0.0054                                                                             0.029                                                                              0.10                                                                               -- -- --  -- -- 0.031                                                                              bal.                                                                              53    11.0 94    460                  5  0.51                                                                              0.29                                                                               0.029                                                                              0.09                                                                               -- -- --  -- -- 0.026                                                                              bal.                                                                              64    8.7  82    515                  6  0.49                                                                              0.11                                                                               0.0012                                                                             0.12                                                                               -- -- --  -- -- 0.033                                                                              bal.                                                                              58    9.0  84    500                  7  0.54                                                                              0.13                                                                               0.046                                                                              0.11                                                                               -- -- --  -- -- 0.021                                                                              bal.                                                                              61    9.6  80    500                  8  0.51                                                                              0.11                                                                               0.030                                                                              0.0011                                                                             -- -- --  -- -- 0.082                                                                              bal.                                                                              59    9.4  85    500                  9  0.52                                                                              0.19                                                                               0.031                                                                              0.29                                                                               -- -- --  -- -- 0.016                                                                              bal.                                                                              60    9.4  87    505                  10 0.44                                                                              0.10                                                                               0.030                                                                              --  0.10                                                                              -- --  -- -- 0.041                                                                              bal.                                                                              58    9.5  83    500                  11 0.46                                                                              0.11                                                                               0.028                                                                              --  -- 0.05                                                                              --  -- -- 0.061                                                                              bal.                                                                              58    9.2  81    505                  12 0.61                                                                              0.09                                                                               0.029                                                                              --  -- -- 0.0019                                                                             -- -- 0.064                                                                              bal.                                                                              60    9.3  85    500                  13 0.62                                                                              0.16                                                                               0.033                                                                              --  -- -- --  0.26                                                                              -- 0.022                                                                              bal.                                                                              61    9.3  87    490                  14 0.52                                                                              0.18                                                                               0.030                                                                              --  -- -- --  -- 0.21                                                                              0.033                                                                              bal.                                                                              59    9.3  86    495                  15 0.50                                                                              0.12                                                                               0.024                                                                              --  0.06                                                                              -- --  0.03                                                                              -- 0.051                                                                              bal.                                                                              58    9.3  82    495                  16 0.50                                                                              0.11                                                                               0.022                                                                              --  -- 0.03                                                                              0.02                                                                               -- 0.04                                                                              0.028                                                                              bal.                                                                              69    9.3  82    500                  17 0.46                                                                              0.18                                                                               0.036                                                                              0.04                                                                               0.02                                                                              -- 0.01                                                                               0.02                                                                              -- 0.041                                                                              bal.                                                                              60    9.5  83    495                  18 0.49                                                                              0.16                                                                               0.030                                                                              0.03                                                                               0.04                                                                              0.02                                                                              0.01                                                                               0.02                                                                              0.02                                                                              0.039                                                                              bal.                                                                              59    9.4  84    500                  __________________________________________________________________________

Example 2

By repeating the procedures of Example 1, sample Nos. 19-42 of the Cu alloy lead material of the present invention were fabricated from melts of Cu alloy having the compositions shown in Table 2. The tensile strength, elongation, electrical conductivity and softening point of each sample were measured, with the results also being shown in Table 2.

As the data in Table 2 shows, each sample had a tensile strength of 65 kgf/mm² or higher, an elongation of 6% or more, an electrical conductivity of 62% IACS or more, and a softening point of 480° C. or higher. These values are indicative of the fact that the samples of the Cu alloy lead material of the present invention exhibit heretofore unattainable high levels of strength and elongation and yet satisfy the other requirements with respect to the characteristics which leads in semiconductor devices need to possess.

                                      TABLE 2                                      __________________________________________________________________________                                                                soften-             Composition (wt. %)                        tensile                                                                              elon-                                                                              conduc-                                                                              ing                 Sample                             impur-  strength                                                                             gation                                                                             tivity                                                                               point               No. Cr Zr  Li  Ni Sn  Ti Si  others                                                                               ities                                                                              Cu  (kgf/mm.sup.2)                                                                       (%) (%                                                                                   (°C.)        __________________________________________________________________________     19  0.052                                                                             0.051                                                                              0.031                                                                              0.51                                                                              0.41                                                                               0.61                                                                              0.04                                                                               P: 0.12                                                                              0.042                                                                              bal.                                                                               65    7.9 64    480                 20  0.56                                                                              0.052                                                                              0.032                                                                              0.46                                                                              0.46                                                                               0.65                                                                              0.05                                                                               P: 0.09                                                                              0.039                                                                              bal.                                                                               73    6.5 67    500                 21  0.98                                                                              0.049                                                                              0.026                                                                              0.41                                                                              0.48                                                                               0.63                                                                              0.03                                                                               P: 0.13                                                                              0.041                                                                              bal.                                                                               80    6.0 69    525                 22  0.54                                                                              0.0051                                                                             0.031                                                                              0.43                                                                              0.42                                                                               0.64                                                                              0.06                                                                               P: 0.10                                                                              0.051                                                                              bal.                                                                               71    6.3 67    495                 23  0.51                                                                              0.091                                                                              0.030                                                                              0.42                                                                              0.46                                                                               0.66                                                                              0.05                                                                               P: 0.11                                                                              0.047                                                                              bal.                                                                               75    6.5 65    505                 24  0.55                                                                              0.048                                                                              0.0013                                                                             0.40                                                                              0.44                                                                               0.60                                                                              0.04                                                                               P: 0.11                                                                              0.051                                                                              bal.                                                                               71    6.2 69    495                 25  0.50                                                                              0.61                                                                               0.046                                                                              0.61                                                                              0.50                                                                               0.58                                                                              0.04                                                                               P: 0.13                                                                              0.036                                                                              bal.                                                                               77    6.8 65    505                 26  0.56                                                                              0.052                                                                              0.030                                                                              0.052                                                                             0.51                                                                               0.61                                                                              0.05                                                                               P: 0.18                                                                              0.029                                                                              bal.                                                                               71    6.3 72    490                 27  0.49                                                                              0.051                                                                              0.026                                                                              0.99                                                                              0.43                                                                               0.66                                                                              0.05                                                                               P: 0.17                                                                              0.031                                                                              bal.                                                                               75    6.7 64    510                 28  0.46                                                                              0.046                                                                              0.028                                                                              0.58                                                                              0.051                                                                              0.62                                                                              0.05                                                                               P: 0.11                                                                              0.040                                                                              bal.                                                                               72    6.4 70    495                 29  0.51                                                                              0.057                                                                              0.027                                                                              0.50                                                                              0.97                                                                               0.46                                                                              0.05                                                                               P: 0.10                                                                              0.042                                                                              bal.                                                                               73    6.6 62    510                 30  0.53                                                                              0.056                                                                              0.029                                                                              0.49                                                                              0.44                                                                               0.054                                                                             0.04                                                                               P: 0.18                                                                              0.028                                                                              bal.                                                                               79    7.1 65    490                 31  0.50                                                                              0.054                                                                              0.025                                                                              0.54                                                                              0.45                                                                               0.94                                                                              0.05                                                                               P: 0.11                                                                              0.037                                                                              bal.                                                                               69    6.0 68    510                 32  0.49                                                                              0.051                                                                              0.026                                                                              0.51                                                                              0.46                                                                               0.61                                                                              0.0011                                                                             P: 0.09                                                                              0.038                                                                              bal.                                                                               72    6.5 65    500                 33  0.47                                                                              0.056                                                                              0.027                                                                              0.52                                                                              0.46                                                                               0.64                                                                              0.095                                                                              P: 0.09                                                                              0.041                                                                              bal.                                                                               74    6.5 69    500                 34  0.54                                                                              0.041                                                                              0.029                                                                              0.51                                                                              0.48                                                                               0.61                                                                              0.04                                                                               Mg: 0.013                                                                            0.056                                                                              bal.                                                                               73    6.4 65    500                 35  0.53                                                                              0.050                                                                              0.023                                                                              0.54                                                                              0.50                                                                               0.54                                                                              0.06                                                                               Al:0.0012                                                                            0.059                                                                              bal.                                                                               74    6.4 63    495                 36  0.51                                                                              0.052                                                                              0.024                                                                              0.52                                                                              0.49                                                                               0.61                                                                              0.06                                                                               Zn: 0.009                                                                            0.030                                                                              bal.                                                                               72    6.5 65    500                 37  0.52                                                                              0.053                                                                              0.026                                                                              0.51                                                                              0.52                                                                               0.63                                                                              0.05                                                                               Mn: 0.29                                                                             0.011                                                                              bal.                                                                               74    6.6 68    505                 38  0.50                                                                              0.050                                                                              0.025                                                                              0.50                                                                              0.53                                                                               0.64                                                                              0.06                                                                               P: 0.010                                                                             0.021                                                                              bal.                                                                               74    6.5 68    500                                              Mn: 0.13                                          39  0.51                                                                              0.049                                                                              0.026                                                                              0.54                                                                              0.52                                                                               0.60                                                                              0.06                                                                               Mg: 0.13                                                                             0.033                                                                              bal.                                                                               73    6.4 68    500                                              Zn: 0.04                                                                       P: 0.08                                           40  0.51                                                                              0.054                                                                              0.026                                                                              0.55                                                                              0.51                                                                               0.58                                                                              0.04                                                                               Mg: 0.07                                                                             0.032                                                                              bal.                                                                               73    6.4 69    505                                              Zn: 0.09                                                                       Al: 0.04                                          41  0.48                                                                              0.053                                                                              0.024                                                                              0.53                                                                              0.49                                                                               0.60                                                                              0.05                                                                               Zn: 0.06                                                                             0.036                                                                              bal.                                                                               74    6.5 68    500                                              Mn: 0.01                                                                       P: 0.01                                           42  0.51                                                                              0.053                                                                              0.023                                                                              0.50                                                                              0.53                                                                               0.59                                                                              0.05                                                                               Al: 0.06                                                                             0.038                                                                              bal.                                                                               75    6.3 69    510                                              Zn: 0.13                                                                       Mn: 0.02                                          __________________________________________________________________________

Example 3

Melts of Cu alloy having the compositions shown in Table 3 were treated as in Example 1 to fabricate hot-rolled plates of 11 mm in thickness. The plates were then quenched with a water spray to reduce the sizes of eutectic crystals and crystalline grains without inducing the formation of any precipitate. The top and bottom surfaces of each plate were polished so as to reduce the plate thickness by 0.5 mm and thus attain a final thickness of 10 mm. Subsequently, the plates were cold-rolled to attain a thickness of 2 mm and fine precipitates were caused to form by aging, this being achieved by holding the plates for 60 minutes at predetermined temperatures within the range of 400-550° C. The aged plates were cold-rolled to attain a further reduction in thickness down to 0.7 mm, and were annealed to eliminate any residual strain by holding them for 60 minutes at predetermined temperatures within the range of 400-500° C. The so treated plates were subjected to the final stage of cold rolling to fabricate sample Nos. 43-59 of the Cu alloy lead material of the present invention each having a thickness of 0.3 mm. The average grain sizes of the eutectic crystals, precipitates and crystalline grains in these samples were measured. Measurements were also conducted with respect to the tensile strength, elongation, electrical conductivity and softening point of each sample. The results are shown in Table 3.

                                      TABLE 3                                      __________________________________________________________________________     Composition (wt. %)            Average grain size (μm)                                                                        elon-    soften-                       metal of                                                                             metal of                                                                             metal of          crys-                                                                              tensile                                                                              ga-                                                                               conduc-                                                                              ing                 Sample    the first                                                                            the second                                                                           the third                                                                               eutectic                                                                            precip-                                                                            talline                                                                            strength                                                                             tion                                                                              tivity                                                                               point               No. Cr Zr group group group Cu crystal                                                                             itate                                                                              grain                                                                              (kgf/mm.sup.2)                                                                       (%)                                                                               (%                                                                                   (°C.)        __________________________________________________________________________     43  0.54                                                                              -- --    --    --    bal.                                                                              8    0.04                                                                               47  52    16.1                                                                              85    405                 44  -- 0.131                                                                             --    --    --    bal.                                                                              9    0.03                                                                               44  50    12.0                                                                              88    400                 45  0.93                                                                              -- Ni: 0.83                                                                             --    --    bal.                                                                              4    0.07                                                                               30  77    6.2                                                                               65    520                 46  0.13                                                                              0.091                                                                             Fe: 0.31                                                                             --    --    bal.                                                                              6    0.10                                                                               47  53    10.5                                                                              82    470                           Co: 0.53                                                             47  0.32                                                                              0.151                                                                             --    Mg: 0.15                                                                             --    bal.                                                                              3    0.04                                                                               37  54    8.6                                                                               83    485                                 Al: 0.21                                                       48  0.64                                                                              -- --    Mn: 0.31                                                                             --    bal.                                                                              5    0.05                                                                               27  63    9.2                                                                               82    465                                 B 0.0016                                                                       Si: 0.30                                                       49  0.41                                                                              0.283                                                                             --    Zn: 0.13                                                                             --    bal.                                                                              5    0.05                                                                               34  65    8.7                                                                               83    515                                 P: 0.005                                                       50  0.50                                                                              0.121                                                                             --    --    Ti: 0.016                                                                            bal.                                                                              6    0.07                                                                               38  58    9.1                                                                               84    505                                       Nb: 0.31                                                 51  0.48                                                                              0.096                                                                             --    --    V : 0.21                                                                             bal.                                                                              7    0.06                                                                               34  60    9.0                                                                               82    510                                       Mo: 0.64                                                                       Ta: 0.25                                                 52  0.052                                                                             0.264                                                                             --    --    Hf: 0.31                                                                             bal.                                                                              4    0.03                                                                               24  51    10.5                                                                              87    470                                       W: 0.52                                                                  Li: 0.03                                                       53  0.31                                                                              0.122                                                                             Sn: 0.33                                                                             Y: 0.42                                                                              --    bal.                                                                              3    0.04                                                                               23  56    9.7                                                                               86    480                           Co: 0.14                                                                             La: 0.10                                                                       Mg: 0.33                                                       54  0.54                                                                              0.231                                                                             Be: 0.0054                                                                           P: 0.016                                                                             --    bal.                                                                              5    0.05                                                                               38  65    8.7                                                                               83    515                                 Ce: 0.24                                                                       B : 0.0016                                                     55  0.83                                                                              -- --    Y: 0.36                                                                              W: 0.96                                                                              bal.                                                                              2    0.03                                                                               25  76    6.0                                                                               66    525                                       Ti: 1.05                                                 56  0.27                                                                              0.290                                                                             --    Al: 0.54                                                                             Mo: 0.54                                                                             bal.                                                                              5    0.06                                                                               41  66    6.8                                                                               67    500                           Ni: 1.54    V: 0.32                                                  57  0.52                                                                              -- Be: 0.013                                                                            --    W: 0.34                                                                              bal.                                                                              4    0.05                                                                               38  72    6.5                                                                               52    500                 58  0.32                                                                              0.090                                                                             Sn: 0.0064                                                                           --    Ta: 0.85                                                                             bal.                                                                              3    0.04                                                                               26  54    9.4                                                                               85    490                           Ni: 0.54                                                                             Mg: 0.13                                                                             Ti: 0.35                                                 59  0.36                                                                              0.126                                                                             Sn: 0.34                                                                             Al: 0.046                                                                            Ce: 0.0063                                                                           bal.                                                                              6    0.07                                                                               34  55    9.4                                                                               81    485                 __________________________________________________________________________

The data in Table 3 shows that each of the samples (Nos. 43-59) of the Cu alloy lead material of the present invention exhibited a tensile strength of 50 kgf/mm² or more, an elongation of 6% or more, an electrical conductivity of 52% IACS or more, and a softening point of 400° C. or higher. These values are indicative of the fact that the samples of the Cu alloy lead material of the present invention exhibit heretofore unattainable high levels of strength and elongation and yet satisfy the other requirements with respect to the characteristics which leads in semiconductor devices need to possess.

Example 4

Melts of Cu alloy having the compositions shown in Table 4 were prepared by the following procedures using a conventional type of low-frequency channel induction-melting furnace: a Cu charge enclosed with graphite plates was melted in an argon atmosphere; after meltdown and when its temperature was risen to a predetermined level between 1220° and l480° C., gas was blown into the melt so as to degas and agitate the melt; the necessary alloying elements were added to the melt under agitation; finally, a carbon monoxide gas was blown such that the content of oxygen as an incidental impurity dropped to 35 ppm or below while the carbon content was adjusted to a predetermined level within the range of 5-60 ppm.

The melts so prepared were subsequently treated in an argon atmosphere as in Example 1 so as to fabricate sample Nos. 60-79 of the Cu alloy lead material of the present invention. The tensile strength, elongation, electrical conductivity and softening point of each sample were measured, the results being shown in Table 4, from which one can see that each sample had a tensile strength of 51 kgf/mm² or more, an elongation of 6.2% or more, an electrical conductivity of 52% IACS and more, and a softening point of 410° C. or higher. These values are indicative of the fact that the samples (Nos. 60-79) of the Cu alloy lead material of the present invention exhibit heretofore unattainable high levels of strength and elongation and yet satisfy the other requirements for leads in semiconductor devices.

                                      TABLE 4                                      __________________________________________________________________________     Composition (wt. %)                             elon-     soften-                            metal of                                                                              metal of                                                                             metal of                                                                               Cu and tensile                                                                              ga- conduc-                                                                              ing                  Sample    C   the first                                                                             the second                                                                           the third                                                                              other  strength                                                                             tion                                                                               tivity                                                                               point                No. Cr Zr (ppm)                                                                              group  group group O.sub.2                                                                          impurities                                                                            (kgf/mm.sup.2)                                                                       (%) (% IACS)                                                                             (°C.)         __________________________________________________________________________     60  -- 0.143                                                                             20  --     --    --    25                                                                               bal.   51    12.1                                                                               86    410                  61  0.34                                                                              0.09                                                                              30  --     --    --    10                                                                               bal.   55    10.3                                                                               79    470                  62  0.33                                                                              0.102                                                                             15  --     --    --    30                                                                               bal.   54    10.0                                                                               87    475                  63  0.83                                                                              0.120                                                                             25  Sn: 0.68                                                                              --    --    15                                                                               bal.   63    8.4 74    520                                Ni: 0.22                                                         64  0.25                                                                              -- 30  Fe: 0.33                                                                              --    --    10                                                                               bal.   58    9.5 72    465                                Be: 0.0059                                                                     Co: 0.96                                                         65  0.54                                                                              -- 25  Be: 0.16                                                                              --    --    15                                                                               bal.   71    6.5 53    505                  66  0.42                                                                              0.203                                                                             30  --     Al: 0.093                                                                            --    10                                                                               bal.   63    8.6 78    500                                       Mg: 0.13                                                  67  0.33                                                                              0.05                                                                              30  --     Si: 0.054                                                                            --    10                                                                               bal.   56    9.6 74    470                                       P: 0.046                                                                       Zn: 1.76                                                  68  -- 0.254                                                                             55  --     Y: 0.13                                                                              --    5 bal.   55    10.9                                                                               68    440                                       Ce: 0.045                                                                      Mn: 0.33                                                  69  0.43                                                                              0.091                                                                             30  --     Li: 0.13                                                                             --    15                                                                               bal.   64    9.0 72    490                                       La: 0.0071                                                                           Ti: 0.12                                            70  -- 0.132                                                                             35  --     --    W: 0.24                                                                              15                                                                               bal.   55    11.9                                                                               78    415                                             V: 0.054                                            71  0.69                                                                              -- 35  --     --    Ta: 0.13                                                                             15                                                                               bal.   72    6.6 52    515                                             Mo: 0.21                                                                       Nb: 1.54                                            72  0.13                                                                              0.0064                                                                            40  --     --    Hf: 0.013                                                                            10                                                                               bal.   55    9.3 65    495                  73  0.34                                                                              -- 40  Ni: 0.33                                                                              Li: 0.43                                                                             --    10                                                                               bal.   61    9.7 74    460                  74  0.71                                                                              -- 25  Be: 0.26                                                                              Al: 0.63                                                                             --    20                                                                               bal.   71    8.0 71    490                                Sn: 0.59                                                                              B: 0.0056                                                               Fe: 0.018                                                        75  0.75                                                                              0.019                                                                             30  Co: 0.19                                                                              --    Ti: 0.69                                                                             25                                                                               bal.   73    6.2 63    480                                Sn: 0.22     Nb: 0.13                                            76  -- 0.291                                                                             25  Ni: 0.34                                                                              --    Ta: 0.29                                                                             20                                                                               bal.   54    9.8 57    455                                Co: 0.20     Mo: 0.26                                            77  -- 0.030                                                                             35  --     Y: 0.13                                                                              Mo: 0.54                                                                             15                                                                               bal.   51    10.3                                                                               76    410                                             W: 0.20                                                                  Al: 0.018                                                 78  0.24                                                                              0.194                                                                             35  --     Mn: 0.22                                                                             V: 0.17                                                                              25                                                                               bal.   61    9.1 76    505                                       P : 0.105                                                                            Ta: 0.86                                                          Ni: 0.22                                                                              Li: 0.064                                                                            Nb: 0.42                                            79  0.53                                                                              0.113                                                                             30  Sn: 0.30                                                                              V: 0.0091                                                                            Hf: 0.41                                                                             25                                                                               bal.   65    8.7 66    510                  __________________________________________________________________________

EXAMPLE 5

Melts of Cu alloy having the compositions shown in Table 5 were prepared by repeating the procedures of Example 4. They were subsequently treated in an argon atmosphere as in Example 3 to fabricate sample Nos. 80-99 of the Cu alloy lead material of the present invention. The average grain sizes of the eutectic crystals, precipitates and crystalline grains in these samples were measured. Measurements were also conducted with respect to the tensile strength, elongation, electrical conductivity and softening point of each sample. The results are shown in Table 6. As is clear from the data in Table 6, each of the samples (Nos. 80-99) of the Cu alloy lead material of the present invention had a tensile strength of 52 kgf/mm² or more, an elongation of 6.2% or more, an electrical conductivity of 53% IACS or more, and a softening point of 410° C. or higher. These values are indicative of the fact that the samples of the Cu alloy lead material of the present invention exhibit heretofore unattainable high levels of strength and elongation and yet satisfy the other requirements for leads in semiconductor devices.

                                      TABLE 5                                      __________________________________________________________________________     Composition (wt. %)                                                            Sample     C   metal of the                                                                          metal of the                                                                          metal of the                                                                            Cu and other                             No  Cr Zr  (ppm)                                                                              first group                                                                           second group                                                                          third group                                                                           O.sub.2                                                                          impurities                               __________________________________________________________________________     80  0.11                                                                              --  25  --     --     --     10                                                                               bal.                                     81  -- 0.123                                                                              30  --     --     --     15                                                                               bal.                                     82  0.53                                                                              --  20  --     --     --     15                                                                               bal.                                     83  0.84                                                                              0.0056                                                                             15  Ni: 1.54                                                                              --     --     20                                                                               bal.                                     84  0.23                                                                              --  25  Sn: 0.13                                                                              --     --     15                                                                               bal.                                                    Be: 0.0059                                                                     Sn: 0.33                                                        85  0.36                                                                              0.032                                                                              10  Fe: 0.41                                                                              --     --     25                                                                               bal.                                                    Co: 0.36                                                        86  0.35                                                                              0.090                                                                              30  --     Si: 0.020                                                                             --     10                                                                               bal.                                                           Mg: 0.54                                                                       Si: 0.13                                                 87  0.64                                                                              --  35  --     Mn: 0.23                                                                              --     10                                                                               bal.                                                           P: 0.14                                                                        Al: 0.0013                                               88  -- 0.264                                                                              50  --     Zn: 0.13                                                                              --     5 bal.                                                           B: 0.021                                                                       Li: 0.0013                                               89  0.43                                                                              0.064                                                                              30  --     Ce: 0.0016                                                                            --     10                                                                               bal.                                                           Y: 0.0011                                                                             Ti: 0.16                                          90  -- 0.154                                                                              35  --     --     Nb: 0.33                                                                              5 bal.                                                                  Mo: 0.21                                                                       V: 0.0094                                         91  0.32                                                                              --  5   --     --     Hf: 0.13                                                                              35                                                                               bal.                                                                  W: 0.41                                                                 La: 0.019                                                92  0.13                                                                              0.104                                                                              15  Ni: 0.14                                                                              Y: 0.024                                                                              --     15                                                                               bal.                                                    Be: 0.23                                                                              P: 0.043                                                 93  0.69                                                                              0.165                                                                              25  Sn: 0.64                                                                              P: 0.13                                                                               --     10                                                                               bal.                                                    Ni: 0.32                                                        94  -- 0.154                                                                              15  Co: 0.14                                                                              --     Mo: 1.96                                                                              20                                                                               bal.                                                    Fe: 0.33                                                                                     V: 0.0063                                         95  0.48                                                                              --  25  Be: 0.0041                                                                            --     W: 0.039                                                                              10                                                                               bal.                                                           Al: 0.41                                                                              Ti: 0.36                                          96  0.12                                                                              0.0064                                                                             20  --     Mn: 0.11                                                                              Ta: 0.21                                                                              15                                                                               bal.                                                           Li: 0.13                                                                              Mo: 0.21                                                                       La: 0.13                                          97  0.30                                                                              --  25  --     Mg: 0.026                                                                             Ce: 0.21                                                                              10                                                                               bal.                                                           P : 0.018                                                                             Zn: 0.41                                                         Co: 0.34                                                                              Mg: 0.31                                                 98  0.79                                                                              --  20  Be: 0.12                                                                              Al: 0.26                                                                              W: 0.65                                                                               15                                                                               bal.                                     99  0.32                                                                              0.060                                                                              30  Sn: 0.064                                                                             Li: 0.0050                                                                            Ti: 0.35                                                                              10                                                                               bal.                                                    Ni: 0.71                                                                              Si: 0.030                                                __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________     Average grain size (μ m)                                                                             elon-                                                                              conduc-                                                                             soften-                                                    crys-                                                                               tensile                                                                              ga- tivity                                                                              ing                                          Sample                                                                             eutectic                                                                             precip-                                                                            talline                                                                             strength                                                                             tion                                                                               (%)  point                                        No. crystal                                                                              itate                                                                              grain                                                                               (kgf/mm.sup.2)                                                                       (%) IACS (°C.)                                 __________________________________________________________________________     80  7     0.07                                                                               43   52    16.4                                                                               85   410                                          81  9     0.10                                                                               47   53    12.2                                                                               85   410                                          82  6     0.04                                                                               42   55    16.2                                                                               83   410                                          83  4     0.03                                                                               26   78    6.5 60   530                                          84  5     0.04                                                                               35   57    9.2 75   465                                          85  8     0.07                                                                               43   66    8.3 68   520                                          86  5     0.03                                                                               37   57    10.7                                                                               78   470                                          87  7     0.08                                                                               46   65    9.3 77   470                                          88  6     0.06                                                                               41   55    10.5                                                                               68   445                                          89  5     0.03                                                                               35   63    9.5 74   475                                          90  5     0.04                                                                               35   56    11.5                                                                               72   435                                          91  8     0.07                                                                               42   60    9.4 70   475                                          92  7     0.06                                                                               41   64    6.6 57   470                                          93  4     0.03                                                                               40   70    6.2 58   515                                          94  4     0.02                                                                               36   67    6.6 53   485                                          95  5     0.04                                                                               35   58    13.7                                                                               75   425                                          96  3     0.02                                                                               23   65    8.6 67   455                                          97  4     0.03                                                                               37   61    8.7 69   480                                          98  4     0.02                                                                               35   76    6.2 55   515                                          99  5     0.03                                                                               42   75    6.4 63   505                                          __________________________________________________________________________

As will be understood from the foregoing description, the device of the present invention has leads which exhibit heretofore unattainable increased levels of strength and elongation and yet retain the levels of electrical conductivity and softening point that are required to be exhibited by ordinary semiconductor devices. Therefore, said semiconductor devices have higher packing densities while exhibiting equally superior performance. 

What is claimed is:
 1. A semiconductor device having leads of high strength and elongation and which consist essentially of a copperalloy that contains 0.05-1% of Cr, 0.005-0.3% of Zr, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of Si and 0.001-0.3% of at least one element selected from the group consisting of P, Mg, Al, Zn and Mn, with the balance being Cu and no more than 0.1% of incidental impurities, the percent being on a weight basis.
 2. A semiconductor device according to claim 1 in which said copper alloy contains 0.005-0.1% of Zr, 0.05-1% of Ni, 0.05-1% of Sn, 0.05-1% of Ti, 0.001-0.1% of Si, the percent being on a weight basis.
 3. A semiconductor device having leads of high strength and elongation and which consist essentially of a copper alloy that contains either 0.05-1% of Cr or 0.005-0.3% of Zr or both, 0.001-0.05% of Li, 0-1% of Ni, 0-1% of Sn, 0-1% of Ti, 0-0.1% of Si and which further contains one or more of 0-2% of a metal selected from the group consisting of Fe, Co and Be, 0-1% of a metal selected from the group consisting of Mg, Al, Zn, Mn, B, P, Y and a rare earth element, and 0-2% of a metal selected from the group consisting of Nb, V, Ta, Hf, Mo and W, the percent being on a weight basis, with the balance being copper and incidental impurities, and which has a structure wherein the average grain size of any eutectic crystal present is no more than 10 μm, the average grain size of any precipitate present is no more than 0.1 μm, and the average size of any crystalline grains present is no more than 50 μm.
 4. A semiconductor device according to claim 3 in which said copper alloy contains 0.005-0.1% of Zr, 0.05-1% of Ni, 0.05-1% of Sn, 0.05-1% of Ti, 0.001-0.1% of Si and which further contains one or more of 0.005-2% of a metal selected from the group consisting of Fe, Co and Be, 0.001-1% of a metal selected from the group consisting of Mg, Zn, Mn, B, P, Y and a rare earth element, and 0.005-2% of a metal selected from the group consisting of Nb, V, Ta, Hf, Mo and W. 